Phosphoramidates containing a p-phenylenediamine group

ABSTRACT

Novel phosphoramidates of the general formula: ##STR1## wherein R, R&#39; and R&#34; represent certain specified substituent groups, are useful as stabilizing agents for organic materials, such as natural and synthetic rubbers and lubricating oils. The combined use of these compounds with certain sulfur-containing compounds shows a surprising synergistic effect.

This is a division of application Ser. No. 399,580, filed July 19, 1982 now U.S. Pat. No. 4,418,022.

BACKGROUND OF THE INVENTION

The present invention relates to novel phosphoramidate compounds containing a p-phenylenediamine group, to compositions containing these compounds for stabilizing organic materials, and to lubricating oils or shaped articles of organic materials containing a stabilizing amount of the composition.

It is well known in the art that many N-substituted paraphenylenediamines posses the serious drawbacks of changing the visual appearance of organic materials which are to be stabilized.

SUMMARY OF THE INVENTION

The present invention provides novel compounds of the general formula: ##STR2## wherein R is a hydrogen atom, a straight-chain or branched-chain alkyl or alkoxy group, or cycloalkyl or cycloalkoxy group containing from 5 to 8 carbon atoms, and wherein R' and R" may be the same or different and each represents a substituted or unsubstituted straight-chain or branched-chain alkyl group having 1 to 22 carbon atoms, a substituted or unsubstituted cycloalkyl group having 5 to 8 carbon atoms, an alkenyl group having 3 to 22 carbon atoms, a substituted or unsubstituted phenyl group, an alkylphenyl group containing from 7 to 14 carbon atoms, or an aralkyl group containing from 7 to 15 carbon atoms, or alternatively wherein R' and R" together are a 1,2- or 1,3-alkylene group containing from 2 to 8 carbon atoms or an o-arylene group containing from 6 to 10 carbon atoms.

The novel compounds of the present invention are particularly useful as antioxidants when incorporated into natural and synthetic rubbers where, unlike conventional p-phenylenediamine antioxidants, they have been found to be non-staining and in certain instances non-pigmenting. Preferred compounds are those in which R is a hydrogen atom and R' and R" are the same or different and each represents an alkyl group containing 1 to 18 carbon atoms, an alkylphenyl group containing 7 to 14 carbon atoms or an aralkyl group containing 7 to 15 carbon atoms, or alternatively wherein R' and R" together are ethylene or o-phenylene. Particularly preferred compounds are those in which R is a hydrogen atom and R' and R" are the same or different and at least one of them represents an ethyl, n-butyl, lauryl or phenyl group. A preferred compound of the invention is a compound of the formula: ##STR3##

The compounds of the present invention are advantageously used in the stabilization of organic materials, such as waxes and synthetic resins, as well as synthetic rubbers of which styrenebutadiene rubber (SBR) and nitrile rubber are exemplary, and especially natural rubber and lubricating oils. In contrast with most known p-phenylenediamine-type antioxidants the present compounds, although derived from the staining antioxidants, are non-staining or stain so slightly as to produce negligible discoloration in the stabilized product, while maintaining a high degree of antioxidant activity.

The antioxidants of the present invention may be employed to produce dispersions or emulsions which are mixed with a rubber latex during coagulation and which protect this latex during subsequent treatment. They need not be added to the rubber at the latex stage, but may instead be used as antioxidants when added to rubber crumb or baled crumbs at the mill or during other fabrication stages. Thus, the compounds of the present invention may be incorporated into an oxidizable organic material, such as natural rubber, in an amount from about 0.005 to 5 parts per 100 parts of material, to afford non-staining compositions having an improved stability towards oxidation by atmospheric oxygen. The compounds of the present invention are also particularly useful for the stabilization of lubricants and either synthetic or petroleum based greases and oils, such as for example aliphatic esters, polyalkylene oxides, silicones, phosphoric acid esters, silicic acid esters and polyfluorinated hydrocarbons. Lubricant oils of petroleum origin into which the antioxidants of the present invention may be incorporated include the motor oils, transmission oils, cutting oils, and hydraulic oils known in the industry. The compounds of the invention may be incorporated into synthetic greases such as alkali metal, alkaline earth metal and aluminum based greases in solid or semi-solid form. Furthermore, the compounds of the present invention may be added to motor fuels that contain saturated and/or unsaturated blends of hydrocarbon materials. The combined use of the products of the invention and certain sulfur-containing compounds is found to have a tremendous synergistic effect in the inhibition of oxidation in lubricating oils.

Sulfur-containing compounds which have a synergistic effect with the compounds of the present invention include sulfur compounds having other uses in lubricating oil formulations. Examples of these sulfur compounds are the disulfides, including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide and dibenzyl disulfide. Other suitable sulfur compounds are sulfurized triisobutylene and benzothiadiazole, and the sulfurized Diels-Alder adducts disclosed in U.S. Pat. No. 3,498,915. Good results are obtained with dibenzyldisulfide, zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurized sperm oil or phosphosulfurized-pinene. A synergistic effect is generally obtained if, per 10 parts by weight of the sulfur compound, the composition contains from 6 to 14 parts by weight of the antidegradant of the present invention. The minimum amount in which either stabilizer must be present in order to give the desired results is generally in the range of from 0.005 to 5% by weight, the amount in which each component is added usually being in the range of 0.2 to 5% by weight.

The compounds of the present invention are manufactured by reacting equimolar amounts of a p-amino-diphenylamine with a halophosphate ester, preferably a chlorophosphate ester. Advantageously, at least an equimolar amount of a tertiary amine such as triethylamine, triisopropylamine or pyridine may be added to neutralize the hydrogen halide acid produced. Examples of suitable solvents in which the reaction may be carried out are: dimethylacetamide, dimethylformamide, tetrahydrofuran, diethyl ether, or dioxane; esters such as ethyl acetate; aromatic hydrocarbons such as benzene or toluene; aliphatic hydrocarbons and mixtures such as hexane, heptane, or ligroin. The starting products are known or can be readily manufactured in accordance with generally known methods.

The manufacture and use of the compounds according to the invention are described in more detail in the following Examples, in which "parts" denotes parts by weight and "%" denotes percentages by weight.

Example I

Diphenylchlorophosphate (127 g.) was dissolved in 50 cm³ dry toluene to form a solution which was added over a period of 1 hour to a stirred mixture of 82.8 g. 4-aminodiphenylamine, 450 cm³ dry toluene and 50 g. triethylamine. The reaction was mildly exothermic, the temperature of the reaction mixture rising from 20° C. to 33° C. while adding the solution. Stirring was continued for a further 18 hours, after which period a thick paste was obtained. The solid was filtered off and partitioned by extraction with chloroform and water. The toluene filtrate was evaporated to dryness under vacuum, and the residue was similarly partitioned between chloroform and water. The two chloroform solutions were combined, dried over anhydrous Na₂ SO₄, and evaporated down to afford a light grey solid in a yield of 94% (175.6 g.) and having a melting point of 126.5°-128° C.

This product can be recrystallized from methanol to give a white crystalline solid having a melting point of 127.5°-128° C. and at a yield of 85% (158.7 g.). Other phosphoramidates can be prepared in an analogous manner.

EXAMPLE II Stabilization of Natural Rubber

The product of Example I (Compound A) was evaluated as an antioxidant in a comparison with Compound B, 2,2'-methylene-bis-(4-methyl-6-tertiarybutyl) phenol, in the following standard rubber formulations:

    ______________________________________                                                               parts by weight                                          ______________________________________                                         Natural Rubber (SMR 5)  100                                                    carbon black            45                                                     zinc oxide              5                                                      stearic acid            3                                                      N--cyclohexyl-2-benzothiazyl sulphenamide                                                              0.5                                                    sulfur                  2.5                                                    antioxidant             0.25-1                                                 ______________________________________                                    

Vulcanization was carried out at 142° C. for 35 minutes. The following physical properties of test samples were measured in accordance with DIN 53504:

    ______________________________________                                         tensile strength (T)                                                                              N/cm.sup.2                                                  elongation at break (E)                                                                           %                                                           modulus (M)        N/cm.sup.2                                                  ______________________________________                                    

After the samples had been subjected to hot air aging at 70° C. for 7 days and to oxygen aging by the method of Bierer and Davis (DIN 53508) for 2 days at 70° C. and at a pressure of 21 atmospheres, the above properties were measured again. The effect on the physical properties of the test samples expressed as a percentage of the initial measured values is shown in Table I. For the long term oxygen aging evaluation the same conditions were used, with the exception that longer test periods were employed. The results expressed as a percentage of the initial measured values are shown in Table II (natural rubber), Table III (carbon black-filled natural rubber after hot air aging at 100° C.) and Table IV (in whiting-filled natural rubber after hot air aging at 100° C.).

The results set forth in these tables clearly show the superior stabilizing properties of the compounds of the present invention, as compared with those of a typical and widely used commercial non-staining antioxidant, 2,2'-methylene-bis-(4methyl-6-tertiarybutyl) phenol (Compound B).

                                      TABLE I                                      __________________________________________________________________________     RETENTION OF PHYSICAL PROPERTIES AFTER AGING                                   __________________________________________________________________________                                          percentage retention of                                  initial data in N/cm  physical properties after                          Concentra-                                                                           × 10            hot air aging                                      tion in %                                                                            TENSILE                                                                               ELONGATION     TENSILE                                                                              ELONGATION                                                                              MODULUS                    ANTIOXIDANT                                                                             by weight                                                                            STRENGTH                                                                              AT BREAK MODULUS                                                                              (T)   (E)      (M)                        __________________________________________________________________________     Compound 0.25  285    386      200   99    106      106                        A        0.5   307    464      190   88    90       114                                 0.75  310    469      197   96    90       117                                 1.0   321    473      205   96    88       106                        Compound 0.25  315    420      232   86    91        93                        B        0.5   321    548      184   88    73       120                                 0.75  305    532      150   101   82       141                                 1.0   321    647      153   92    62       143                        without  --    280    397      192   98    94       111                        antioxidant                                                                    __________________________________________________________________________                                          percentage retention of                                                        physical properties after                                                Concentra-                                                                           oxygen aging                                                             tion in %                                                                            TENSILE                                                                              ELONGATION                                                                              MODULUS                                          ANTIOXIDANT                                                                             by weight                                                                            (T)   (E)      (M)                        __________________________________________________________________________                           Compound 0.25  86    164      58                                               A        0.5   83    87       91                                                        0.75  89    91       102                                                       1.0   85    87       92                                               Compound 0.25  29    56       51                                               B        0.5   48    67       69                                                        0.75  64    77       101                                                       1.0   69    70       99                                               without  --    15     8       205                                              antioxidant                                              __________________________________________________________________________

                                      TABLE II                                     __________________________________________________________________________     RETENTION OF PHYSICAL PROPERTIES AFTER LONG TERM OXYGEN AGING                                      PERCENTAGE RETENTION OF PHYSICAL                                               PROPERTIES AFTER OXYGEN AGING FOR                                   CONCENTRATION                                                                             5 days   10 days  15 days                                  ANTIOXIDANT                                                                             % BY WEIGHT                                                                               T  E  M  T  E  M  T  E  M                                  __________________________________________________________________________     A        0.25       69.0                                                                              70.4                                                                              74.3                                                                              29.3                                                                              61.1                                                                              40.0                                                                              17.4                                                                              31.6                                                                              0                                           0.5        73.8                                                                              83.6                                                                              91.9                                                                              52.4                                                                              82.9                                                                              70.2                                                                              33.6                                                                              80.0                                                                              37.8                                        0.75       75.9                                                                              88.5                                                                              92.5                                                                              57.7                                                                              82.4                                                                              75.0                                                                              46.3                                                                              83.3                                                                              39.0                                        1.0        80.1                                                                              87.7                                                                              47.8                                                                              62.5                                                                              66.1                                                                              30.4                                                                              48.7                                                                              87.8                                                                              53.5                               B        0.25        4.4                                                                               9.8                                                                              0  0  0  0  0  0  0                                           0.5         6.9                                                                              11.5                                                                              13.2                                                                              0  0  0  0  0  0                                           0.75       22.3                                                                              28.2                                                                              18.9                                                                              0  0  0  0  0  0                                           1.0        23.7                                                                              27.8                                                                              18.9                                                                              0  0  0  0  0  0                                  Without  --         0  0  0  0  0  0  0  0  0                                  Antioxidant                                                                    __________________________________________________________________________

                                      TABLE III                                    __________________________________________________________________________                         PERCENTAGE RETENTION OF PHYSICAL                                               PROPERTIES AFTER HOT AIR AGING AT                                              100° C. FOR                                                  CONCENTRATION                                                                             1 day  3 days 5 days 7 days                                ANTIOXIDANT                                                                             % BY WEIGHT                                                                               T E M  T E M  T E M  T E M                                 __________________________________________________________________________     Compound A                                                                              1.0        82                                                                               80                                                                               107                                                                               38                                                                               50                                                                               105                                                                               28                                                                               40                                                                               105                                                                               24                                                                               29                                                                               154                                        0.5        75                                                                               77                                                                               113                                                                               33                                                                               49                                                                               95 22                                                                               38                                                                                96                                                                               19                                                                               24                                                                               147                                        0.3        76                                                                               81                                                                               106                                                                               30                                                                               52                                                                               92 18                                                                               30                                                                               110                                                                               19                                                                               24                                                                               184                               Compound B                                                                              2.0        73                                                                               77                                                                               112                                                                               33                                                                               45                                                                               139                                                                               23                                                                               30                                                                               140                                                                               28                                                                               25                                                                               212                                        1.0        65                                                                               68                                                                               114                                                                               31                                                                               47                                                                               88 21                                                                               29                                                                               118                                                                               20                                                                               22                                                                               176                                        0.5        71                                                                               71                                                                               113                                                                               33                                                                               49                                                                               87 23                                                                               34                                                                               105                                                                               22                                                                               26                                                                               147                               __________________________________________________________________________      (100° C. hot air aging of antioxidants in carbon blackfilled            natural rubber)                                                          

                                      TABLE IV                                     __________________________________________________________________________                         PERCENTAGE RETENTION OF PHYSICAL                                               PROPERTIES AFTER HOT AIR AGING AT                                              100° C. FOR                                                  CONCENTRATION                                                                             1 day  3 days 5 days 7 days                                ANTIOXIDANT                                                                             % BY WEIGHT                                                                               T E M  T E M  T E M  T E M                                 __________________________________________________________________________     Without             55                                                                               87                                                                                95                                                                               17                                                                               61                                                                                81                                                                                8                                                                               47                                                                               --  8                                                                               25                                                                               --                                Antioxidant                                                                    Compound A                                                                              1.0        88                                                                               93                                                                               107                                                                               72                                                                               84                                                                               124                                                                               65                                                                               79                                                                               125                                                                               32                                                                               62                                                                               136                                        0.5        87                                                                               92                                                                               108                                                                               56                                                                               79                                                                               121                                                                               49                                                                               74                                                                               123                                                                               19                                                                               51                                                                               131                                        0.3        88                                                                               93                                                                               105                                                                               55                                                                               77                                                                               120                                                                               31                                                                               64                                                                               124                                                                               23                                                                               55                                                                               125                               Compound B                                                                              2.0        84                                                                               87                                                                               120                                                                               55                                                                               75                                                                               134                                                                               39                                                                               68                                                                               138                                                                               18                                                                               49                                                                               143                               __________________________________________________________________________      (100° C. hot air aging of antioxidants in whitingfilled natural         rubber)                                                                  

Example III

In this Example a comparison is made between N-isopropyl-N'-phenyl-p-phenylenediamine (compound C), an antidegradant widely used by the rubber industry and known to cause severe migration staining, and the following phophoramidates according to the invention:

N-(p-phenylaminophenyl)diethyl phosphoramidate (compound D);

N-(p-phenylaminophenyl)diphenyl phosphoramidate (compound A);

N-(p-phenylaminophenyl)dilauryl phosphoramidate (compound E); and

N-(p-phenylaminophenyl)di-n-butyl phosphoramidate (compound F).

The above compounds were characterized by IR and NMR; the following melting points were measured:

    ______________________________________                                         Compound D          111°-112° C.;                                Compound E          waxy solid;                                                Compound F          45° C.                                              ______________________________________                                    

The above compounds were evaluated in carbon black-loaded natural rubber. The heat resistance and oxygen resistance in accordance with DIN 53508 were measured and the results compared with those obtained with compound C.

The staining test was also performed with the above compounds, and the results compared with those obtained using compound C and expressed as a percentage of the activity of the blank. In the staining test the extent to which a stabilizer tends to migrate from the rubber vulcanizate and cause discoloration upon its contact with light colored objects is measured. The rubber samples to be tested to that end contained either no stabililzer or one of the compounds C, D, A, E and F. The rubber samples were contacted with white rubber for 7 days.

The results are given in the following Table V and expressed as a percentage of the activity of the blank:

                                      TABLE V                                      __________________________________________________________________________     STAINING, HEAT RESISTANCE AND OXYGEN RESISTANCE OF ANTIOXIDANTS                IN CARBON BLACK-LOADED NATURAL RUBBER                                                              HEAT       OXYGEN                                                              RESISTANCE AS                                                                             RESISTANCE AS                                                       COMPARED WITH                                                                             COMPARED WITH                                                                             % STAINING RELATIVE                           CONCENTRATION                                                                             COMPOUND C COMPOUND C TO BLANK                             ANTIOXIDANT                                                                             % BY WEIGHT                                                                               T   E  M   T   E  M   (100% = NON-STAINING)                __________________________________________________________________________     COMPOUND C                                                                              1          100 100                                                                               100 100 100                                                                               100 32                                   (comparison)                                                                   COMPOUND D                                                                              1          98  97 106  97 107                                                                               103 99                                            2          101 94  83 106 105                                                                               104 100                                  COMPOUND A                                                                              1          99  99 101 103 103                                                                                93 100                                           2          91  91  99  94  98                                                                                93 99                                   COMPOUND E                                                                              1          99  100                                                                                99  99 109                                                                                88 98                                            2          91  93  97  93 100                                                                                89 98                                   COMPOUND F                                                                              1          95  93 103 102 100                                                                               102 96                                            2          96  94 104  93  95                                                                                94 89                                   __________________________________________________________________________

EXAMPLE IV Stabilization of Mineral Oil

0.25 g. of the product of Example I (compound A) was dissolved in 49.75 g. of a mineral oil (solvent-refined paraffin base oil Risella 33, a product of the Royal Dutch/Shell Group). The solution was heated to 175° C. and air passed through it at a rate of 5 liters/hour in an open system. The induction time to oxidation was measured by oxygen analysis of the effluent gas flow. N-isopropyl-N-phenyl-p-phenylene-diamine (compound C) was used as a standard and the results are given in Table VI.

                  TABLE VI                                                         ______________________________________                                         Mineral oil + antioxidant                                                                          induction time (mins.)                                     ______________________________________                                         without antioxidant  10                                                        0.5% by weight of compound A                                                                       660                                                        0.5% by weight of compound C                                                                       510                                                        0.5% by weight of compound D                                                                       600                                                        0.5% by weight of compound E                                                                       1260                                                       ______________________________________                                    

EXAMPLE V

This example demonstrates the stabilization of mineral oil in the presence of a synergistic amount of a sulfur compound and a phosphoramidate according to the invention. The procedure described in Example IV was repeated using 0.5% (w/w) dibenzyldisulfide (compound P) as additive, and mixtures of compounds (A) and (P), totaling 0.5% by weight. The results are given in Table VII.

                  TABLE VII                                                        ______________________________________                                                       Compound P                                                       Compound A (% w/w)                                                                           (% w/w)     Induction time (hours)                               ______________________________________                                         0.5           0           11.0                                                 0.4           0.1         50.0                                                 0.3           0.2         67.0                                                 0.25          0.25        73.0                                                 0.2           0.3         55.0                                                 0.1           0.4         46.5                                                 0             0.5         2.0                                                  ______________________________________                                     

What is claimed is:
 1. A composition for stabilizing an organic material such as waxes, natural and synthetic rubbers, synthetic resins, and lubricating oils, comprising:(a) a phosphoramidate compound of the general formula: ##STR4## wherein R is a hydrogen atom, a straight-chain or branched-chain alkyl or alkoxy group, or cycloalkyl or cycloalkoxy group containing from 5 to 8 carbon atoms, and wherein R' and R" may be the same or different and each represents a substituted or unsubstituted straight-chain or branched-chain alkyl group having 1 to 22 carbon atoms, a substituted or unsubstituted cycloalkyl group having 5 to 8 carbon atoms, an alkenyl group having 3 to 22 carbon atoms, a substituted or unsubstituted phenyl group, an alkylphenyl group containing from 7 to 14 carbon atoms, or an aralkyl group containing from 7 to 15 carbon atoms, or alternatively wherein R' and R" together are a 1,2- or 1,3-alkylene group containing from 2 to 8 carbon atoms or an o-arylene group containing from 6 to 10 carbon atoms; and (b) a synergistic amount of a sulfur compound.
 2. A composition for stabilizing an organic material, comprising:(a) the phosphoramidate compound as set forth in claim 1, wherein R is a hydrogen atoms and R' and R" are the same or different and each represent an alkyl group containing 1 to 18 carbon atoms, an alkylphenyl group containing 7 to 14 carbon atoms or an aralkyl group containing 7 to 15 carbon atoms, or alternatively wherein R' and R" together are ethylene or o-phenylene; and (b) a synergistic amount of a sulfur compound.
 3. A composition for stabilizing an organic material, comprising:(a) the phosphoramidate compound as set forth in claim 1, wherein R is a hydrogen atom and R' and R" are the same or different and at least one of them is selected from the group including the ethyl, n-butyl, lauryl or phenyl group; and (b) a synergistic amount of a sulfur compound.
 4. A composition as claimed in claim 1, which comprises from 6 to 14 parts by weight of said sulfur compound per 10 parts by weight of said phosphoramidate compound.
 5. A composition as claimed in claim 2, which comprises from 6 to 14 parts by weight of said sulfur compound per 10 parts by weight of said phosphoramidate compound.
 6. A composition as claimed in claim 3, which comprises from 6 to 14 parts by weight of said sulfur compound per 10 parts by weight of said phosphoramidate compound.
 7. A composition as set forth in claim 1, wherein the sulfur compound is selected from the group including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide, or dibenzyl disulfide.
 8. A composition as set forth in claim 1, wherein the sulfur compound is selected from the group including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide, or dibenzyl disulfide.
 9. A composition as set forth in claim 3, wherein the sulfur compound is selected from the group including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide, or dibenzyl disulfide.
 10. A composition as set forth in claim 4, wherein the sulfur compound is selected from the group including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide, or dibenzyl disulfide.
 11. A composition as set forth in claim 5, wherein the sulfur compound is selected from the group including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide, or dibenzyl disulfide.
 12. A composition as set forth in claim 6, wherein the sulfur compound is selected from the group including di-n-butyl disulfide, dicyclohexyl disulfide, 2,2'-(dicarboethoxy)diethyl disulfide, or dibenzyl disulfide.
 13. A composition as set forth in claim 1, wherein the sulfur compound is selected from the group including zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurised sperm oil or phosphosulfurised-pinene.
 14. A composition as set forth in claim 2, wherein the sulfur compound is selected from the group including zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurised sperm oil or phosphosulfurised-pinene.
 15. A composition as set forth in claim 3, wherein the sulfur compound is selected from the group including zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurised sperm oil or phosphosulfurised-pinene.
 16. A composition as set forth in claim 4, wherein the sulfur compound is selected from the group including zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurised sperm oil or phosphosulfurised-pinene.
 17. A composition as set forth in claim 5, wherein the sulfur compound is selected from the group including zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurised sperm oil or phosphosulfurised-pinene.
 18. A composition as set forth in claim 6, wherein the sulfur compound is selected from the group including zinc dialkyldithiophosphates, zinc diaryldithiophosphates, sulfurised sperm oil or phosphosulfurised-pinene.
 19. An organic material such as waxes, natural and synthetic rubbers, synthetic resins, and lubricating oils subject to oxidative degradation and containing a phosphoramidate compound of the general formula: ##STR5## wherein R is a hydrogen atom, a straight-chain or branched-chain alkyl or alkoxy group, or cycloalkyl or cycloalkoxy group containing from 5 to 8 carbon atoms, and wherein R' and R" may be the same or different and each represents a substituted or unsubstituted straight-chain or branched-chain alkyl group having 1 to 22 carbon atoms, a substituted or unsubstituted cycloalkyl group having 5 to 8 carbon atoms, an alkenyl group having 3 to 22 carbon atoms, a substituted or unsubstituted phenyl group, an alkylphenyl group containing from 7 to 14 carbon atoms, or an aralkyl group containing from 7 to 15 carbon atoms, or alternatively wherein R' and R" together are a 1,2- or 1,3-alkylene group containing from 2 to 8 carbon atoms or an o-arylene group containing from 6 to 10 carbon atoms.
 20. The organic material as set forth in claim 19, wherein R is a hydrogen atom and R' and R" are the same or different and each represent an alkyl group containing 1 to 18 carbon atoms, an alkylphenyl group containing 7 to 14 carbon atoms or an aralkyl group containing 7 to 15 carbon atoms, or alternatively wherein R' and R" together are ethylene or o-phenylene.
 21. The organic material as set forth in claim 19, wherein R is a hydrogen atom and R' and R" are the same or different and at least one of them is selected from the group including the ethyl, n-butyl, lauryl or phenyl group.
 22. An organic material subject to oxidative degradation and containing a stabilizer composition as set forth in claim
 1. 23. An organic material subject to oxidative degradation and containing a stabilizer composition as set forth in claim
 2. 24. An organic material subject to oxidative degradation and containing a stabilizer composition as set forth in claim
 3. 25. An organic material subject to oxidative degradation and containing a stabilizer composition as set forth in claim
 4. 26. An organic material subject to oxidative degradation and containing a stabilizer composition as set forth in claim
 5. 27. An organic material subject to oxidative degradation and containing a stabilizer composition as set forth in claim
 6. 28. An organic material such as waxes, natural and synthetic rubbers, synthetic resins, and lubricating oils subject to oxidative degradation and containing 0.005 to 5 parts by weight of at least one phosphoramidate compound per 100 parts by weight of said organic material, said phosphoramidate compound being of the general formula: ##STR6## wherein R is a hydrogen atom, a straight-chain or branched-chain alkyl or alkoxy group, or cycloalkyl or cycloalkoxy group containing from 5 to 8 carbon atoms, and wherein R' and R" may be the same or different and each represents a substituted or unsubstituted straight-chain or branched-chain alkyl group having 1 to 22 carbon atoms, a substituted or unsubstituted cycloalkyl group having 5 to 8 carbon atoms, an alkenyl group having 3 to 22 carbon atoms, a substituted or unsubstituted phenyl group, an alkylphenyl group containing from 7 to 14 carbon atoms, or an aralkyl group containing from 7 to 15 carbon atoms, or alternatively wherein R' and R" together are a 1,2- or 1,3-alkylene group containing from 2 to 8 carbon atoms or an o-arylene group containing from 6 to 10 carbon atoms.
 29. The organic material set forth in claim 28, wherein in said phosphoramidate compound, R is a hydrogen atom and R' and R" are the same or different and each represent an alkyl group containing 1 to 18 carbon atoms, an alkylphenyl group containing 7 to 14 carbon atoms or an aralkyl group containing 7 to 15 carbon atoms, or alternatively wherein R' and R" together are ethylene or o-phenylene.
 30. The organic material set forth in claim 28, wherein in said phosphoramidate compound, R is a hydrogen atom and R' and R" are the same or different and at least one of them is selected from the group including the ethyl, n-butyl, lauryl or phenyl group.
 31. The organic material set forth in claim 28, further containing a synergistic amount of a sulfur compound per 100 parts by weight of said organic material.
 32. The organic material set forth in claim 29, further containing a synergistic amount of a sulfur compound per 100 parts by weight of said organic material.
 33. The organic material set forth in claim 30, further containing a synergistic amount of a sulfur compound per 100 parts by weight of said organic material. 